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Gibbs Free Energy and Thermodynamic Favorability

Sophie Anderson

Sophie Anderson

7 min read

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Study Guide Overview

This study guide covers thermodynamic favorability and spontaneity of reactions. Key concepts include enthalpy (ΔH°), entropy (ΔS°), and Gibbs Free Energy (ΔG°). It explains how to calculate ΔG° using the formula ΔG° = ΔH° - TΔS° and standard free energies of formation. The guide also discusses conditions influencing spontaneity and distinguishes between entropy-driven and enthalpy-driven reactions, including practice problems and exam tips.

Thermodynamic Favorability: Is It Going to Happen? 🤔

Hey, future AP Chem master! Let's dive into thermodynamic favorability, which is all about predicting whether a reaction will occur spontaneously. Think of it like this: is the reaction naturally inclined to happen, or does it need a push? Let's find out!

This topic is crucial for understanding reaction spontaneity and equilibrium, which are major themes in AP Chemistry. Expect to see these concepts in both multiple-choice and free-response questions.

Explaining Thermodynamic Favorability

Thermodynamic favorability helps us determine if a reaction is spontaneous (happens on its own) or nonspontaneous (needs external help). Spontaneous reactions are thermodynamically favorable, while non-spontaneous ones are thermodynamically unfavorable.

Key Concept

Spontaneity is directly linked to the equilibrium constant. A spontaneous reaction tends to favor product formation.

Enthalpy (ΔH°) and Entropy (ΔS°): The Dynamic Duo

Two main factors determine spontaneity:

  1. Enthalpy Change (ΔH°): This is the heat change in a reaction.
    • Exothermic (ΔH° < 0): System loses heat to surroundings. Think of it as 'heat exiting'. 🔥

    • Endothermic (ΔH° > 0): System gains heat from surroundings. Think of it as 'heat entering'. 🧊

Enthalpy Change

*Caption: Visualizing exothermic and endothermic reactions. Exothermic reactions release heat, while endothermic reactions absorb it.*

2. Entropy Change (ΔS°): This is the change in disorder or randomness of a system. * Positive ΔS°: Disorder increases. More chaos! 🎉 * Negative ΔS°: Disorder decreases. More order. 😥

Quick Fact

Reactions that increase entropy are exentropic, and those that decrease entropy are endentropic. These terms are less common on the AP exam but good to know. ...