All Flashcards
What is the effect of a negative value?
The reaction is exothermic, releasing heat to the surroundings.
What is the effect of a positive value?
The reaction is endothermic, absorbing heat from the surroundings.
What happens when heat is added to a substance with a high heat capacity?
The temperature of the substance increases less than a substance with a low heat capacity.
Describe the process of calorimetry.
Measure the initial temperature of reactants and calorimeter, conduct the reaction inside the calorimeter, measure the final temperature, and calculate the heat released or absorbed using .
How do you calculate enthalpy using bond enthalpies?
Sum of bond energies broken minus the sum of bond energies formed: .
How do you calculate enthalpy using enthalpies of formation?
Sum of enthalpies of formation of products minus the sum of enthalpies of formation of reactants: .
Explain Hess's Law.
If a reaction can be expressed as a series of steps, the enthalpy change for the overall reaction is the sum of the enthalpy changes for each step. Manipulate individual reactions (reversing or multiplying) to match the target reaction.
Differentiate between exothermic and endothermic reactions in terms of and heat flow.
Exothermic: , heat is released. Endothermic: , heat is absorbed.
Compare calculating using bond enthalpies versus enthalpies of formation.
Bond Enthalpies: Uses bond breaking and forming energies. Enthalpies of Formation: Uses standard enthalpies of formation of products and reactants.