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What is the difference between Ksp and Qsp?
Ksp: The solubility product constant, an equilibrium constant. Qsp: The ion product, calculated using initial concentrations to predict precipitation.
Define solubility.
The extent to which a substance dissolves in a solvent, reaching an equilibrium between the solid and its ions in solution.
What is Ksp?
The solubility product constant; the equilibrium constant for the dissolution of a solid in a solution.
What does a high Ksp indicate?
A highly soluble compound; the dissolution reaction proceeds far to the right.
What does a low Ksp indicate?
A poorly soluble compound; the dissolution reaction barely proceeds to the right.
Define molar solubility.
The concentration of the metal cation in a saturated solution.
Define ion product (Qsp).
The ion product is a measure of the relative amount of ions in a solution. It predicts whether a precipitate will form.
What are the steps to calculate Ksp from solubility (g/L)?
- Write the dissolution reaction. 2. Convert solubility from g/L to mol/L (Molarity). 3. Plug molarity into the Ksp expression: Ksp = [ion1]^coefficient * [ion2]^coefficient.
What are the steps to calculate molar solubility from Ksp?
- Write the dissolution reaction. 2. Set up a RICE table. 3. Plug equilibrium concentrations (in terms of 'x') into the Ksp expression. 4. Solve for 'x', which represents the molar solubility.
How do you predict precipitation using Qsp and Ksp?
- Calculate Qsp using initial ion concentrations. 2. Compare Qsp to Ksp: If Qsp > Ksp, precipitation occurs. If Qsp < Ksp, no precipitation occurs. If Qsp = Ksp, the solution is at equilibrium.