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Describe the general steps to solve for pH of a weak acid solution using an ICE table.

  1. Write the equilibrium reaction. 2. Set up the ICE table. 3. Write the KaK_a expression. 4. Solve for x (=[H⁺]). 5. Calculate pH = -log[H⁺].
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Describe the general steps to solve for pH of a weak acid solution using an ICE table.

  1. Write the equilibrium reaction. 2. Set up the ICE table. 3. Write the KaK_a expression. 4. Solve for x (=[H⁺]). 5. Calculate pH = -log[H⁺].

Describe the general steps to solve for pH of a weak base solution using an ICE table.

  1. Write the equilibrium reaction. 2. Set up the ICE table. 3. Write the KbK_b expression. 4. Solve for x (=[OH⁻]). 5. Calculate pOH = -log[OH⁻]. 6. Calculate pH = 14 - pOH.

What is the Arrhenius definition of an acid?

Acids produce H⁺ ions in water.

What is the Arrhenius definition of a base?

Bases produce OH⁻ ions in water.

What is the Bronsted-Lowry definition of an acid?

Acids are proton (H⁺) donors.

What is the Bronsted-Lowry definition of a base?

Bases are proton acceptors.

Define a strong acid.

Acids that completely dissociate in water (virtually 100% ionization).

Define a strong base.

Bases that completely dissociate in water.

Define a weak acid.

Acids that incompletely dissociate in water; they exist in equilibrium between the undissociated and dissociated forms.

Define a weak base.

Bases that incompletely dissociate in water; they exist in equilibrium between the undissociated and dissociated forms.

Define chemical equilibrium.

A dynamic state where forward and reverse reactions occur at the same rate; there is no net change in concentrations of reactants and products.

What does a large equilibrium constant (K) indicate?

The reaction favors products.

What does a small equilibrium constant (K) indicate?

The reaction favors reactants.

Define KaK_a.

The acid dissociation constant; a measure of the strength of a weak acid. Ka=[H+][A][HA]K_a = \frac{[H^+][A^-]}{[HA]}

Define KbK_b.

The base dissociation constant; a measure of the strength of a weak base. Kb=[BH+][OH][B]K_b = \frac{[BH^+][OH^-]}{[B]}

What are the key differences between strong acids and weak acids?

Strong acids: Completely dissociate, have negligible conjugate base strength. | Weak acids: Partially dissociate, have conjugate bases with measurable strength.

What are the key differences between strong bases and weak bases?

Strong bases: Completely dissociate, have negligible conjugate acid strength. | Weak bases: Partially dissociate, have conjugate acids with measurable strength.

Compare and contrast KaK_a and KbK_b.

KaK_a: Acid dissociation constant, measures acid strength. | KbK_b: Base dissociation constant, measures base strength. | Both: Smaller values indicate weaker acids/bases.