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  1. AP Chemistry
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Glossary

A

Anions

Criticality: 2

Negatively charged ions formed when an atom gains one or more electrons.

Example:

A sulfide ion (S2-) is an anion that is larger than a neutral sulfur atom because it has gained electrons, increasing electron-electron repulsion.

Atomic Radius

Criticality: 3

The distance from the nucleus to the outermost electron shell of a neutral atom.

Example:

Cesium has a much larger atomic radius than lithium because it has more electron shells.

C

Cations

Criticality: 2

Positively charged ions formed when an atom loses one or more electrons.

Example:

When a magnesium atom loses two electrons, it forms a Mg2+ cation, which is smaller than the neutral magnesium atom.

E

Effective Nuclear Charge (Zeff)

Criticality: 3

The net positive charge experienced by an electron in an atom, accounting for the shielding effect of inner electrons.

Example:

As you move from left to right across a period, the increasing effective nuclear charge pulls the valence electrons closer, reducing atomic size.

Electronegativity

Criticality: 3

The ability of an atom to attract electrons towards itself in a chemical bond.

Example:

Oxygen has a high electronegativity, causing it to strongly pull shared electrons towards itself in a water molecule, creating a polar bond.

G

Groups (Columns)

Criticality: 2

Vertical columns on the periodic table where elements share the same number of valence electrons, leading to similar chemical properties.

Example:

Elements in Group 1, like lithium and cesium, are alkali metals and all have one valence electron, making them highly reactive.

I

Ionic Radius

Criticality: 2

The distance from the nucleus to the outermost electron shell of an ion.

Example:

The ionic radius of a chloride ion (Cl-) is larger than that of a neutral chlorine atom due to increased electron-electron repulsion.

P

Periods (Rows)

Criticality: 2

Horizontal rows on the periodic table where elements share the same number of electron shells.

Example:

All elements in the fourth period, such as potassium and bromine, possess four occupied electron shells.