Thermochemistry
What is Bond Dissociation Energy (BDE)?
The energy released when a bond is formed.
The energy required to break a specific bond.
The average kinetic energy of molecules in a gas.
The potential energy stored in a molecule.
Given the following bond energies: C-H (413 kJ/mol), O=O (498 kJ/mol), C=O (799 kJ/mol), and O-H (463 kJ/mol), what is the enthalpy change for the following reaction?
-802 kJ/mol
+802 kJ/mol
-401 kJ/mol
+401 kJ/mol
Which of the following statements accurately describes the energy changes associated with breaking and forming chemical bonds?
Breaking bonds releases energy, while forming bonds requires energy.
Breaking bonds requires energy, while forming bonds releases energy.
Both breaking and forming bonds require energy.
Both breaking and forming bonds release energy.
How does the Bond Dissociation Energy (BDE) typically vary between single, double, and triple bonds between the same two atoms?
Single bond > Double bond > Triple bond
Single bond = Double bond = Triple bond
Triple bond > Double bond > Single bond
Double bond > Triple bond > Single bond
Consider the following carbon-halogen bonds: C-F, C-Cl, C-Br, and C-I. Rank these bonds in terms of their Bond Dissociation Energies (BDE) from highest to lowest.
C-I > C-Br > C-Cl > C-F
C-F > C-Cl > C-Br > C-I
C-Cl > C-F > C-Br > C-I
C-Br > C-I > C-F > C-Cl
Is the following step endothermic or exothermic: ?
Exothermic
Endothermic
Neither
Both
Determine the enthalpy change (ΔH) for the combustion of ethane () to form carbon dioxide and water, given the following average bond enthalpies: C-C = 347 kJ/mol, C-H = 414 kJ/mol, O=O = 498 kJ/mol, C=O = 799 kJ/mol, and O-H = 463 kJ/mol. Note: You will need to determine the balanced chemical equation first.
-1427 kJ/mol
-2854 kJ/mol
-312 kJ/mol
+1427 kJ/mol

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Given the following approximate bond energies: H-H = 432 kJ/mol, H-Cl = 427 kJ/mol, what is the approximate enthalpy change (ΔH) for the reaction if the bond energy for Cl-Cl is 242 kJ/mol?
-185 kJ/mol
+247 kJ/mol
+185 kJ/mol
-247 kJ/mol