Acids and Bases
What is the formula for calculating pH if the concentration of hydrogen ions ([H+]) in a solution is known?
pH = 14 + log[OH-]
pH = [H+]^2
pH = log[H+]
pH = -log[H+]
Which component do you need to calculate using the Henderson-Hasselbalch equation for a buffer solution?
The product of hydrogen ion concentration and hydroxide ion concentration.
The ratio of conjugate base concentration to acid concentration.
The sum of all solute concentrations in solution.
The difference in molarity between strong acids and strong bases in solution.
In the Henderson-Hasselbalch equation, what is the relationship between the pH of a solution and the pKa when the concentrations of an acid and its conjugate base are equal?
The pH equals the pKa.
The pH is less than the pKa.
The pH is greater than the pKa.
The pH has no relation to pKa.
Given equal molecular masses, what is the primary reason that polar substances generally have higher boiling points than nonpolar substances?
Greater molar mass in polar substances
Stronger dipole-dipole interactions in polar substances
Weaker dispersion forces in nonpolar substances
Lower kinetic energy at a given temperature for polar substances
In an efficient buffer system composed predominantly of NH₄Cl (NH₄⁺), if the nitrous acid (HNO₂) is present as a weak acid with a pKa of 3.35 and pH is adjusted to an optimal buffering range, how would the pH compare to the aforementioned pKa?
Higher than 3.35 but within one unit
Exactly equal to pKa, regardless of buffer composition
Less than 3.35 by at least two units
Two lower than 3.35 but not more than one unit
What is the primary role of buffer systems as related to the Henderson-Hasselbalch equation?
Maintaining temperature within a biological system
Maintaining constant pH within biological systems
Ensuring the solubility of proteins within biological systems
Providing nutrients to target cells within a biological system
If you have a buffer solution containing a weak base with pKb = 3.70 and its salt at concentrations [B] = [HB+], what will be its approximate pH?
The pH will be approximately 3.70.
The pH will be approximately 10.30.
The pH will be approximately 7.
Additional information is needed for calculation.

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A solution of acetic acid has a pH of 6.75. The ratio of acid to conjugate base is _______________. (pKa = 4.75)
100:1
100:0.1
1899-12-30T09:16:36.000Z
0.1:100
Why does ethylene glycol have a higher boiling point than ethanol despite having a lower molecular weight?
Higher polarity causing stronger dipole-dipole interactions
Lower vapor pressure indicating weaker overall intermolecular forces
More extensive hydrogen bonding per molecule
Greater dispersion forces due to increased surface area
Which change would NOT affect the validity of using the Henderson-Hasselbalch equation for a buffered solution?
Doubling both concentrations of weak acid and its conjugate base in the solution.
Changing the color indicator used in titration experiments.
Adding a strong acid that exceeds the buffering capacity.
Halving both concentrations of weak base and its conjugate acid in the solution.