Intermolecular Forces and Properties
What is the term for a substance that increases the rate of a chemical reaction without being consumed in the process?
Reactant
Catalyst
Product
Solvent
Given that the solubility product (Ksp) values vary across different salts, which of these factors best accounts for an anomalously low Ksp in some transition metal hydroxides?
High charge density leading to increased lattice energy
Larger atomic radii decreasing ion-dipole interactions
Smaller ion sizes reducing crystal defect formation
Lower hydration enthalpy for larger ions
When comparing salts containing common ions, what could predictably affect their respective Ksp values?
Differences in lattice energy due to varying ion charges and sizes
The phase at room temperature between various salts
The difference in melting points between salts
The color change when each salt is dissolved in water
What type of intermolecular force is primarily responsible for the solubility of NaCl in water?
London dispersion forces
Hydrogen bonding
Dipole-dipole forces
Ion-dipole forces
What occurs when an ionic compound dissolves in water?
The compound forms covalent bonds with water molecules.
The compound precipitates out of the solution.
The water molecules form an alloy with the compound.
The compound dissociates into its ions.
Which of the following best explains why molecular compounds with polar covalent bonds are generally more soluble in polar solvents than in nonpolar solvents?
The strong hydrogen bonding between the polar molecules and the solvent molecules make it easier for the molecular compound to dissolve in polar solvents.
The strong dipole-dipole interactions between the polar molecules and the solvent molecules make it easier for the molecular compound to dissolve in polar solvents.
The weak van der Waals interactions between the polar molecules and the solvent molecules make it difficult for the molecular compound to dissolve in nonpolar solvents.
The strong covalent bonding between the polar molecules and the solvent molecules make it easier for the molecular compound to dissolve in polar solvents.
Which transition metal cation is most likely to have a lower solubility for its sulfide salt in water due to the formation of a more stable half-filled d subshell?
Mn^2+
Co^2+
Fe^2+
Ni^2+

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For which type of solid will an increase in temperature typically result in decreased solubility?
Molecular solid with hydrogen bonding interactions
Ionic solid with an endothermic dissolution process
Nonpolar molecular solid with induced dipole forces
Ionic solid with an exothermic dissolution process
What effect does increasing temperature generally have on Ksp value and therefore relative insoluble salt solubility?
Generally increases both Ksp value and solubility.
Decreases soluble salt content without affecting Ksp value.
Increases Ksp but has no direct relationship with soluble salt content.
Generally decreases both Ksp values and solubility.
What is a supersaturated solution?
A solution that contains the maximum amount of solute that can dissolve at a given temperature.
A solution with less solute than can be dissolved at a specific temperature
A homogeneous mixture where the particles are evenly mixed and the solute is uniformly distributed within the solvent.
A solution where more solute than can normally be dissolved in the solvent is present.