Kinetics
How might an experiment be formulated to assess the influence of solvent viscosity on reaction mechanism and rate constant determination?
Investigating conductivity changes during electrolysis using different salt solutions as electrolytes.
Measuring and comparing rate constants for nucleophilic substitution reactions conducted in solvents with varying viscosities.
Recording pH shifts when diluting strong acids with solvents possessing different dielectric constants.
Analyzing enthalpy changes by conducting exothermic reactions within calorimeters containing various solvent densities.
Given the following reaction {NO2 + F2 → NO2F + F}, we know that rate = k[NO2][F2]2 . What is the order of the reaction relative to each reactants, and what is the overall reaction order?
NO2 = 0, F2 = 2, Overall = 2
NO2 = 1, F2 = 2, Overall = 2
NO2 = 0, F2 = 1, Overall = 1
NO2 = 1, F2 = 2, Overall = 3
When a catalyst is added to a chemical reaction, what immediate effect does it have on one key component?
It lowers activation energy.
It decreases product concentrations.
It increases activation energy.
It raises enthalpy change (∆H) for reactions.
How does adding a catalyst affect both an endothermic and an exothermic reaction's activation energy?
A catalyst raises activation energy for both types of reactions.
A catalyst lowers activation energy for endothermic but raises it for exothermic reactions.
A catalyst has no effect on activation energies for either type of reactions.
A catalyst lowers activation energy for both types of reactions.
What observation indicates that an elementary step within a proposed mechanism is second-order with respect to one reactant?
Doubling this reactant’s concentration leads directly to quadrupling this step's observed rate when others are held steady.
Observing direct Quadruple Increase Step's Observed Rate When One Reactant Is Doubled Indicative being Second Order Respect
Halving This Reactant's Concentration results in Doubles amount Time required For Product formation To Begin Steady State Conditions Are Maintained throughout Experimentation Process Changes Observed Over Time Seem Impeccable Of Initial Concentrations involved
Doubling this Reactant’ s Concentration results In no Change In Overall Reaction Rate Under Steady conditions.
For which compound would you expect dispersion forces to play the most significant role in determining its physical properties?
Carbon dioxide (COâ‚‚)
Oxygen (Oâ‚‚)
Hydrogen peroxide (Hâ‚‚Oâ‚‚)
Iodine (Iâ‚‚)
Which change will NOT affect the rate of a chemical reaction governed by a first-order rate law?
Raising the temperature.
Increasing the concentration of reactants.
Reducing reactant particle size.
Adding a catalyst irrelevant to the reaction pathway.

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A reaction has a rate law of the following: R = k [A][B]. What is the overall order of reaction?
1st
4th
3rd
2nd
The rate law for the following reaction is R = k[XY]^2. The initial rate of the reaction was found to be 0.16 mol/Ls when the initial concentration of XY is 0.40 mol/L. What is the value of the rate constant, k?
k1 = 10.7 s^-1
k1 = 1.000 M8s^-1
k1 = 5403 M^0.5 * s^0.5
k1 = 1.23 x 10^-6 M^-1*s^-1
How does increasing temperature generally affect the activation energy required for chemical reactions?
It decreases activation energy and increases kinetic energy.
It has no effect on either activation or kinetic energies but speeds up reactions by other means.
It does not change activation energy but increases kinetic energy allowing more particles to overcome it.
It increases both activation energy and kinetic energy.