Oxidation-Reduction (Redox) Reactions

Caleb Thomas
7 min read
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Study Guide Overview
This study guide covers redox reactions, focusing on the transfer of electrons and changes in oxidation states. It explains oxidation (loss of electrons) and reduction (gain of electrons), and how to assign oxidation numbers. Balancing redox reactions in both acidic and basic solutions is detailed, along with practice problems and exam tips.
#Redox Reactions: The Ultimate Guide
Hey there, future AP Chem master! 🌟 Let's dive into redox reactions, the final boss of this unit. Remember, you've already conquered precipitation and acid-base reactions – you got this! 💪
#What are Redox Reactions?
Redox reactions, short for oxidation-reduction reactions, are all about the transfer of electrons between atoms, leading to changes in their oxidation states. Think of it as a game of electron hot potato! 🥔
An oxidation state is like an atom's charge in a compound, showing how many electrons it has gained or lost compared to its neutral state. It's a number, positive or negative, that helps us track electron movement.
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Oxidation: When an atom loses electrons, its oxidation number increases. It's like going up a level! ⬆️
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Reduction: When an atom gains electrons, its oxidation number decreases. It's like going down a level! ⬇️
Electrons always travel from the oxidized species to the reduced species. Remember, oxidation and reduction always happen together – you can't have one without the other!
#Quick Recap:
- Redox reactions involve electron transfer.
- Oxidation is losing electrons (oxidation number increases).
- Reduction is gaining electrons (oxidation number decreases).
- The oxidized substance "donates" electrons to the reduced substance.
Writing out redox reactions shows us exactly how electrons are being transferred. Let's get into the nitty-gritty!
Mnemonic Time! Pick your favorite:
- OIL RIG: Oxidation Is Loss, Reduction Is Gain
- LEO says GER: Loss of Electrons = Oxidation, Gain of Electrons = Reduction
#Assigning Oxidation Numbers
To figure out who's gaining and who's losing, we need to assign oxidation numbers. Here are the rules:
- Free Elements: (like Br₂, Na, P₄) have an oxidation number of 0.
- Neutral Molecules: The oxidation numbers of all atoms sum to 0. For example, in IF₆, if iodine's oxidation number is x and fluorine's is y, then x + 6y = 0. 3. Monatomic Ions: The oxidation number equals the ion's charge (e.g., Na⁺ is +1, Cl⁻ is -1).
- Oxygen: Usually -2, except in peroxides (H₂O₂, O₂⁻²) where it's -1.
- Hydrogen: Usually +1, except in metal hydrides (LiH, BaH₂) where it's -1.
- Fluorine: Always -1. Other halogens are usually -1 but can vary.
- Fractions: Oxida...

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