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Free Energy of Dissolution

Sophie Anderson

Sophie Anderson

8 min read

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Study Guide Overview

This study guide covers thermodynamics and its relation to solubility. Key concepts include enthalpy (ΔH), entropy (ΔS), and Gibbs Free Energy (ΔG). It explains how these concepts determine reaction spontaneity and how they apply to the dissolution process. Practice questions and exam tips are also provided.

Unit 7: Solubility and Thermodynamics - Your Ultimate Review 🚀

Hey there, future AP Chem master! Let's break down the final part of Unit 7, where solubility meets the fascinating world of thermodynamics. This is where we see how energy drives whether things dissolve or not. No stress, we've got this! 💪

Thermodynamics: The Driving Force Behind Reactions

Thermodynamics is all about energy transfer during chemical reactions. It's not just about heat; it's about the bigger picture of energy flow. Remember, we're talking about energy, not just temperature or heat. Heat is just one piece of the puzzle.

We've already touched on enthalpy (ΔH) in Unit 6, which tells us if a reaction is exothermic (heat-releasing, ΔH < 0) or endothermic (heat-absorbing, ΔH > 0). Now, let's add two more critical players: entropy (ΔS) and Gibbs Free Energy (ΔG). These are the keys to understanding why reactions happen (or don't!).

Entropy (ΔS): The Measure of Disorder 🌪️

Entropy is all about disorder or randomness in a system. Think of it as the number of possible arrangements. The more spread out and chaotic a system is, the higher its entropy. Systems naturally tend towards higher entropy, like a messy room. It takes energy to make things more ordered.

Phase changes are a great example:

H₂O(s) ⇌ H₂O(l) ⇌ H₂O(g)

As we go from solid to liquid to gas, entropy increases because the molecules have more freedom to move around. Going the other way, from gas to liquid to solid, entropy decreases.

Entropy

_Entropy increases as substances move from solid to liquid to gas._
Memory Aid

Think of it like this:

  • Solid: Super organized, like a neat stack of books (low entropy).
  • Liquid: A bit more spread out, like books scattered on a table (medium entropy).
  • Gas: Totally chaotic, like books thrown all over the room (high entropy).

Gibbs Free Energy (ΔG): The Spontaneity Predictor ✨

Gibbs Free Energy combines enthalpy (ΔH) and entropy (ΔS) to determine if a reaction is thermodynamically favorable (sp...