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Calculating the Equilibrium Constant

Caleb Thomas

Caleb Thomas

9 min read

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Study Guide Overview

This study guide covers calculating equilibrium constants (Kc and Kp). It explains the formulas, provides example calculations, and discusses the meaning of K values. The guide also includes tips for calculations, a sample AP question, and practice problems with an answer key. Key concepts include equilibrium, stoichiometric coefficients, partial pressures, and molar concentrations.

Chemical Equilibrium: Calculating Equilibrium Constants

Introduction

Now that you're familiar with the concepts of KcK_c and KpK_p, let's dive into how to calculate them! This guide will help you master these calculations, ensuring you're ready for anything the AP Chemistry exam throws your way. Remember, equilibrium is all about the balance between reactants and products. Let's get started!

Equilibrium calculations are a cornerstone of AP Chemistry. Expect to see them in both multiple-choice and free-response questions. Mastering this topic is crucial for a strong exam performance.

Equilibrium Constant Formulas

Key Concepts

  • Equilibrium: A state where the rate of forward and reverse reactions are equal, and the concentrations of reactants and products remain constant.

  • KcK_c (Equilibrium Constant in terms of concentration): Relates the concentrations of reactants and products at equilibrium.

  • KpK_p (Equilibrium Constant in terms of pressure): Relates the partial pressures of gaseous reactants and products at equilibrium.

Key Concept

Remember, solids and pure liquids are NOT included in the equilibrium expression. Only aqueous solutions and gases are considered.

Formulas

Both KcK_c and KpK_p follow the same basic formula: products over reactants, each raised to the power of their stoichiometric coefficients. The difference lies in whether you're using concentrations (for KcK_c) or partial pressures (for KpK_p).

KcK_c Formula

latex
<math-block>K\_c = \frac{[C]^c[D]^d}{[A]^a[B]^b}</math-block>

Where:

  • [A], [B] are the equilibrium concentrations of reactants.
  • [C], [D] are the equilibrium concentrations of products.
  • a, b, c, d are the stoichiometric coefficients from the balanced chemical equation.

KpK_p Formula

latex
<math-block>K\_p = \frac{P\_C^cP\_D^d}{P\_A^aP\_B^b}</math-block>

Where:

  • PAP_A, PBP_B are the partial pressures of reactants at equilibrium.

  • PCP_C, PDP_D are the partial pressures of products at equilibrium.

  • a, b, c, d are the stoichiometric coefficients from the balanced chemical equation.

Exam Tip

Pay close attention to the units! KcK_c uses molar concentrations (mol/L), while KpK_p uses partial pressures (usually in atm).

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Question 1 of 10

Given the reaction: N2(g)+3H2(g)2NH3(g)N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g), which of the following is the correct KcK_c expression? 🎉

Kc=[N2][H2]3[NH3]2K_c = \frac{[N_2][H_2]^3}{[NH_3]^2}

Kc=[NH3]2[N2][H2]3K_c = \frac{[NH_3]^2}{[N_2][H_2]^3}

Kc=[NH3][N2][H2]K_c = \frac{[NH_3]}{[N_2][H_2]}

Kc=[N2][H2][NH3]K_c = \frac{[N_2][H_2]}{[NH_3]}