Electrolysis and Faraday's Law

Caleb Thomas
8 min read
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Study Guide Overview
This study guide covers nonspontaneous redox reactions and electrolytic cells. It reviews how electrolytic cells use an external power source to drive these reactions, contrasting them with galvanic cells. Faraday's Law is explained, with examples of how to calculate mass deposited during electrolysis. Finally, key differences between electrolytic and galvanic cells are summarized, emphasizing the importance of anode, cathode, and electron flow.
#π Congratulations on Reaching the Final Stretch! π
You've conquered so much in AP Chemistry, from acids and bases to equilibrium and thermodynamics. Now, let's tackle the last topic: nonspontaneous redox reactions and electrolytic cells. This is where we use external power to make the impossible happen!
#Review of Electrolytic Cells π
Electrolytic cells use an external power source (like a battery) to drive **nonspontaneous redox reactions**. This is the opposite of galvanic cells, which generate electricity from spontaneous reactions. Think of it like pushing a ball uphillβit requires energy input.
Key Concept: Electrolytic cells force reactions to go in the non-spontaneous direction by supplying electrical energy.
Let's look at a classic example:
Caption: In this electrolytic cell, electrons are forced from Cu to Zn, causing Cu to oxidize and Zn to reduce, which is the reverse of the spontaneous reaction.
Normally, copper wouldn't oxidize to form Cu2+, and Zn2+ wouldn't reduce to form Zn metal. However, by applying external voltage, we can make this happen! The reaction is: **Cu + Zn2+ β Cu2+ + Zn**
Calculating Cell Potential (Ecell):
Half-reactions:
Cu β Cu2+ + 2e- (E = -0.34 V)
Zn2+ + 2e- β Zn (E = -0.76 V)
Ecell = -0.34 V + (-0.76 V) = -1.10 V
The negative Ecell confirms that this reaction is nonspontaneous, and we need a battery with voltage greater than 1.10V to drive it.
Remember, the external voltage must be greater than the absolute value of the negative Ecell to overcome the non-spontaneity.
In this setup, the mass of the copper electrode will decrease, and the mass of the zinc electrode will increase, as copper is oxidized and zinc is reduced.
#Comparing Electrolytic and Galvanic Cells
Let's compare galvanic (voltaic) and electrolytic cells side-by-side:

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