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Unit 9 Review: Applications of Thermodynamics

Caleb Thomas

Caleb Thomas

7 min read

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Study Guide Overview

This study guide covers Unit 9 Thermodynamics in AP Chemistry, focusing on energy and spontaneity of reactions. Key topics include: entropy (S°) as a measure of disorder, Gibbs Free Energy (ΔG°) to determine spontaneity, and its relationship with enthalpy (ΔH). The guide also explores the connection between ΔG°, equilibrium constant (K), and electrochemistry concepts like galvanic and electrolytic cells. It includes practice questions and emphasizes important exam tips.

AP Chemistry: Unit 9 - Thermodynamics - The Final Frontier! 🚀

Hey there, future AP Chem master! You've made it to the last unit – Thermodynamics! This is where we tie together a lot of what you've learned, focusing on energy, spontaneity, and how reactions actually happen. Let's make sure you're ready to ace this!

Introduction to Thermodynamics

Thermodynamics is all about energy and whether a reaction will occur on its own (spontaneity). Forget just temperature; we're diving into the heart of why things happen!

  • System: Where the reaction/process is happening.
  • Surroundings: Everything outside the system.
  • Universe: System + Surroundings.
Key Concept

Spontaneity is key! A spontaneous process occurs without needing continuous outside help. Think of a ball rolling downhill – that's spontaneous. Rolling uphill? Not spontaneous!

We'll be exploring:

  • Entropy (S°): A measure of disorder.
  • Gibbs Free Energy (ΔG°): Determines spontaneity.
  • Enthalpy (ΔH): Remember this from Unit 6? It's back!

Major Topics in Unit 9

9.1-9.2: Entropy (S°)

Entropy (S°) is all about disorder. The more chaotic a system, the higher its entropy.

  • High Entropy: More disorder (e.g., gas > liquid > solid).
  • Low Entropy: More order.
Quick Fact

Reactions can either increase (more disorder) or decrease (more order) entropy.

markdown-image

Image: Entropy increases as a substance changes from solid to liquid to gas.

Memory Aid

Think of your room: a clean room is low entropy, a me...

Question 1 of 12

A student is carefully observing a reaction happening inside a test tube. 🎉 What would be considered the 'system' in this scenario?

The test tube itself

The solutions being mixed inside the test tube

The entire laboratory

The air surrounding the test tube